IRON, COBALT AND NICKEL: COMPARATIVE STUDY
Group VIII (old name) of the extended form of the periodic table consists of nine elements arranged in three triads, including the elements of groups 8, 9 and 10.
| Period | Group | ||
| 8 | 9 | 10 | |
| 4 | Fe | Co | Ni |
| 5 | Ru | Rh | Pd |
| 6 | Os | Ir | Pt |
Though the elements in vertical columns are treated as families, these nine elements are treated in a different manner. Fe, Co, and Ni have marked ‘horizontal’ similarities; therefore, these three are treated as a ‘family.’ The other six elements, properties somewhat different from the first horizontal triad, are studied together. Fe, Co and Ni are called ferrous metals. The members of the second and third triads are collectively known as platinum metals or noble metals.
Comparison of Fe, Co and Ni
(i) These three elements have nearly the same atomic masses and resemble closely in their properties. In addition, there is a gradation in their properties.
(ii) Electronic configurations: These atoms have incomplete 3d sub levels.
Fe | 26 | [Ar] | 3d6 4s2 |
Co | 27 | [Ar] | 3d7 4s2 |
Ni | 28 | [Ar] | 3d8 4s2 |
In each atom, the 4s sublevel is complete, and the d sublevel is incomplete; therefore, these are transition elements.
(iii) Valency: These elements show variable valency; +II (ous) and +III (ic) species are formed.
Fe(II) | 3d6 | Fe(III) | 3d5 |
Co(II) | 3d7 | Co(III) | 3d6 |
Ni(II) | 3d8 | Ni(III) | 3d8 |
The stability of the M2+ cations increases from Fe2+ to Ni²+. The 3d5 (half-filled) configuration for Fe³+ is responsible for it being more stable than Fe²+. Removing a 3d electron from the M2+ cations to oxidise them to the M³+ cations becomes more difficult from Fe²+ to Ni2+. Thus, the stability of the M³+ cations is in the order Fe³+ > Co³+ > Ni³+. Almost all the stable compounds of nickel are Ni(II) compounds.
Occurrence
Fe is widely present in nature. Its essential ores are hemetite (Fe2O3), magnetite (Fe3O4) and siderite (FeCO3); iron pyrite (FeS2) is another common mineral of iron. The core of the Earth is believed to consist mainly of iron. Cobalt also occurs in considerable amounts in nature. Smaltite (CoAs2) and cobaltite (CoAsS) are its chief ores. Nickel occurs mainly as sulphides and arsenides. Pentlandite [(NiFe)S] is a commercially important nickel ore.
Physical Properties
The three metals are hard, greyish-white metals of high densities. They have high melting points. All three metals are ferromagnetic; they are strongly attracted by a magnet and remain magnetized even after removing the magnetic field. The ferromagnetic nature decreases from iron to nickel. Their ionisation energies (I₁) are almost the same; hence, they have the same tendency to form ions.
| Properties | Mn | Tc | Re |
|---|---|---|---|
| Atomic Number | 26 | 27 | 28 |
| Electronic Configuration | [Ar] 3d6 4s2 | [Ar] 4d7 5s2 | [[Ar] 4f14 5d5 6s2 |
| Metallic radius (nm) | 0.126 | 0.125 | 0.124 |
| M2+ radius (nm) | 0.076 | 0.074 | 0.072 |
| M3+ radius (nm) | 0.064 | 0.063 | - |
| I1 (kJ mol-1) | 762 | 758 | 736 |
| I2 (kJ mol-1) | 1561 | 1644 | 1752 |
| Melting point (K) | 1808 | 1760 | 1728 |
| Density | 7.9 | 8.9 | 8.9 |
Halides
All three metals form their dihalides. Fe forms FeF3, FeCl3, and FeBr3, but not FeI3. FeI3 is unstable and gets reduced to FeI2. Co forms only the trifluorides and not the other trihalides. Ni does not form any stable trihalides.
Oxides
The oxides formed by iron are
FeO; iron(II) oxide; ferrous oxide
Fe2O3; iron(III) oxide; ferric oxide; hematite
Fe3O4; iron(II) iron(III) oxide; FeO.Fe2O3; ferrosoferric oxide; magnetite
All three are nonstoichiometric.
Cobalt forms only two oxides, CoO and Co3O4, and Nickel forms only one oxide, NiO. However, Ni forms NiO(OH) on oxidation of Ni2+ with aqueous hypobromite.
The oxides of Fe, Co and Ni combine with oxides of a few other metals to form ferrites, for example, ZnFe2O4, CdFe2O4 and Fe₂NiO4. Ferrites are used in electromagnetic devices.
Complexes
These three metals form a large variety of complexes. Several theories of coordination chemistry were developed based on studies of complexes of these metals. Some typical complexes of these metals are:
|
Ion |
Formula of the complex | Magnetic Behaviour | Geometry |
|---|---|---|---|
| Fe2+(d6) |
[Fe(CN)6]4-, [Fe(phen)3]2+ Fe(H₂O)62+ FeX42 |
Diamagnetic Diamagnetic Paramagnetic Paramagnetic |
Octahedral Octahedral Octahedral Tetrahedral |
| Fe3+(d5) |
Fe(CN)62- [Fe(phen)3]3+ Fe(CNS)63- [Fe(C₂O4)3]3- |
Paramagnetic Paramagnetic Paramagnetic Paramagnetic |
Octahedral Octahedral Octahedral Octahedral |
| Co2+(d7) |
Co(H2O)62+ CoCl42- Co(CN)53- |
Paramagnetic Paramagnetic Paramagnetic |
Octahedral Tetrahedral Square Pyramidal |
| Co3+(d6) |
Co(NH3)63+ Co(CN)63- CoF63- |
Diamagnetic Diamagnetic Paramagnetic |
Octahedral Octahedral Octahedral |
| Ni2+(d8) |
[NiCl4]2- [Ni(H2O)6]2+ [Ni(CN)4]2- |
Paramagnetic Paramagnetic Diamagnetic |
Tetrahedral Octahedral Square planar |
| Ni3+(d7) |
[NiCl4]2- [Ni(H2O)6]2+ [Ni(CN)4]2- |
Paramagnetic Paramagnetic Diamagnetic |
Tetrahedral Octahedral Square planar |
| Ni3+(d7) |
NiX3(PMe3)2 [NiF6]3- |
Paramagnetic Paramagnetic |
Trigonal bipyramidal Octahedral |
| Ni4+(d6) | [NiF6]2- | Paramagnetic | cell4_8 |
Uses
All three elements have a great tendency to form alloys with each other and also with other metals. Such alloys are used extensively in industries for making several materials.
Wootz steel (Fe + C) makes Damascus sword and garden tools.
Alnico (Al + Ni + Co) is used to make permanent magnets.
Manganin (Ni + Co +Mn) is used to make an electrical resistance coil.
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Salah satu alasan utama mengapa banyak trader memilih Exness
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broker lainnya. Ini memungkinkan, para trader bisa mendapatkan keuntungan yang
lebih besar, bahkan pada transaksi dengan volume kecil.
Tidak hanya itu, Exness juga menawarkan berbagai jenis akun yang dapat disesuaikan dengan berbagai gaya trading.
Bagi mereka yang baru mulai, Exness memiliki akun dengan setoran awal yang sangat terjangkau, sehingga
siapa saja bisa mulai trading tanpa risiko besar. Bagi trader berpengalaman, Exness menawarkan akun dengan leverage tinggi,
yang memungkinkan mereka untuk memperbesar potensi keuntungan mereka.
Exness dikenal dengan eksekusi order yang sangat cepat dan akurat.
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terutama bagi trader yang melakukan trading harian atau scalping.
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sehingga Anda tidak akan melewatkan peluang pasar yang berharga.
Keunggulan lain yang ditawarkan Exness adalah akses
ke berbagai instrumen keuangan, termasuk forex,
saham, indeks, dan cryptocurrency. Dengan berbagai pilihan ini, trader dapat memilih
instrumen yang sesuai dengan keahlian mereka dan mengembangkan portofolio yang lebih beragam.
Tidak hanya itu, Exness juga memberikan akses ke berbagai alat analisis teknikal dan fundamental yang dapat membantu trader membuat keputusan yang lebih baik dan lebih cerdas.
Keamanan adalah prioritas utama di Exness. Exness terdaftar oleh berbagai otoritas keuangan terkemuka di dunia,
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Dengan sistem keamanan yang canggih dan perlindungan terhadap data pribadi dan dana trader, Anda bisa
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Exness telah lama menjadi pilihan utama bagi banyak trader di seluruh dunia,
dan kini semakin populer di Indonesia. Karena berbagai
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Mari kita bahas lebih dalam tentang alasan mengapa Exness layak dipertimbangkan sebagai broker trading utama Anda.
Salah satu alasan utama mengapa banyak trader memilih Exness adalah
spread rendah yang mereka tawarkan. Dalam dunia trading, biaya transaksi sangat penting, dan Exness menawarkan spread yang jauh lebih rendah dibandingkan dengan banyak broker lainnya.
Dengan biaya transaksi yang lebih rendah, para trader bisa mendapatkan keuntungan yang lebih besar, bahkan pada transaksi dengan volume kecil.
Tidak hanya itu, Exness juga menawarkan berbagai jenis
akun yang dapat disesuaikan dengan berbagai gaya trading.
Bagi mereka yang baru mulai, Exness memiliki akun dengan setoran awal yang sangat terjangkau, sehingga
siapa saja bisa mulai trading tanpa risiko besar.
Bagi mereka yang lebih berpengalaman, Exness menawarkan akun dengan leverage tinggi, yang memungkinkan mereka untuk memperbesar potensi keuntungan mereka.
Exness dikenal dengan eksekusi order yang sangat cepat dan akurat.
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yang melakukan trading harian atau scalping. Dengan teknologi canggih dan platform yang stabil, Exness memastikan bahwa
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Dengan berbagai pilihan ini, trader dapat memilih instrumen yang sesuai dengan keahlian mereka dan mengembangkan portofolio yang
lebih beragam. Tidak hanya itu, Exness juga memberikan akses ke berbagai alat analisis teknikal dan fundamental yang dapat membantu trader membuat keputusan yang lebih baik dan lebih cerdas.
Keamanan adalah prioritas utama di Exness. Exness terdaftar
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dilakukan aman dan terjamin. Dengan sistem keamanan yang canggih dan perlindungan terhadap data pribadi dan dana trader, Anda bisa bertrading dengan tenang.
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Dengan berbagai fitur unggulan ini, Exness adalah broker
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